Numerous large deposits are formed by multiple mineralization events, however, how to identify superimposed mineralization events are poorly understood. The Xiangdong deposit is a large quartz vein-hosted W–Sn deposit within the Dengfuxian composite granite in South China. Previous studies have suggested that there are two discrete W–Sn mineralization events in the deposit. Characterizing the timing of cassiterite precipitation and the physiochemical conditions of the two mineralization events, however, is poorly understood. To address these ambiguities, this contribution characterized the microtextures, trace-element chemistry, and geochronology of cassiterite assemblages within W–Sn-rich quartz veins. Based on cathodoluminescence (CL) images, cassiterite crystals were classified into two types based on textural differences — Cst 1 and Cst 2. Cassiterite 1 is subhedral to irregular and exhibits complex zonation, whereas Cst 2 is euhedral and exhibits oscillatory zonation. Trace-element concentrations and maps of cassiterite obtained via LA–ICP–MS indicate that Cst 1 has high Fe, W, U, and Sb, but low Nb, Ta, and Zr concentrations, whereas Cst 2 has high Nb, Ta, and Zr, but low Fe, W, U, and Sb concentrations. This indicates that Cst 2 formed from higher temperature and more oxidizing hydrothermal fluids than Cst 1. Laser ablation ICP–MS U–Pb geochronological results of Cst 1 and Cst 2 demonstrate these texturally distinct cassiterite precipitated at 150.0 ± 2.6 Ma and 136.3 ± 5.5 Ma, respectively. This contribution demonstrates that integrated textural and compositional studies of cassiterite assemblages are critical to identifying hydrothermal events that superimposed W–Sn mineralization, and to constrain ore-forming mechanisms and the physicochemical conditions of the environment.

Superimposed mineralization;,Cassiterite;,U–Pb geochronology;,W–Sn deposit;,LA–ICP–MS mapping;,South China.